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The town was founded in 1874 by George Vice, and laid out the next year. The town was the setting of South Africa's first coal mine. Its name has connections both locally to the people of the Eastern Cape (Molteno is a surname among the Xhosa speaking people of the district), but it also has Italian roots.

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The largest coal deposits in South Africa are to be found in the Ecca deposits, a stratum of the Karoo Supergroup, dating from the Permian period, between 280 and 250 Ma.The Ecca Group is extensive, covering around two thirds of South Africa (much of it covered by slightly younger rocks - …

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